By now you should be well aware of the correlation between electrical conductivity and certain types of materials. Those materials allowing for easy passage of free electrons are called conductors, while those materials impeding the passage of free electrons are called insulators.

Unfortunately, the scientific theories explaining why certain materials conduct and others don’t are quite complex, rooted in quantum mechanical explanations in how electrons are arranged around the nuclei of atoms. Contrary to the well-known “planetary” model of electrons whirling around an atom’s nucleus as well-defined chunks of matter in circular or elliptical orbits, electrons in “orbit” don’t really act like pieces of matter at all. Rather, they exhibit the characteristics of both particle and wave, their behavior constrained by placement within distinct zones around the nucleus referred to as “shells” and “subshells.” Electrons can occupy these zones only in a limited range of energies depending on the particular zone and how occupied that zone is with other electrons. If electrons really did act like tiny planets held in orbit around the nucleus by electrostatic attraction, their actions described by the same laws describing the motions of real planets, there could be no real distinction between conductors and insulators, and chemical bonds between atoms would not exist in the way they do now. It is the discrete, “quantitized” nature of electron energy and placement described by quantum physics that gives these phenomena their regularity.

Excited-state Atom

When an electron is free to assume higher energy states around an atom’s nucleus (due to its placement in a particular “shell”), it may be free to break away from the atom and comprise part of an electric current through the substance.

Ground-state Atom

If the quantum limitations imposed on an electron deny it this freedom, however, the electron is considered to be “bound” and cannot break away (at least not easily) to constitute a current. The former scenario is typical of conducting materials, while the latter is typical of insulating materials.

Some textbooks will tell you that an element’s electrical conductivity is exclusively determined by the number of electrons residing in the atoms’ outer “shell” (called the valence shell), but this is an oversimplification, as any examination of conductivity versus valence electrons in a table of elements will confirm. The true complexity of the situation is further revealed when the conductivity of molecules (collections of atoms bound to one another by electron activity) is considered.

A good example of this is the element carbon, which comprises materials of vastly differing conductivity: graphite and diamond. Graphite is a fair conductor of electricity, while diamond is practically an insulator (stranger yet, it is technically classified as a semiconductor, which in its pure form acts as an insulator, but can conduct under high temperatures and/or the influence of impurities). Both graphite and diamond are composed of the exact same types of atoms: carbon, with 6 protons, 6 neutrons and 6 electrons each. The fundamental difference between graphite and diamond being that graphite molecules are flat groupings of carbon atoms while diamond molecules are tetrahedral (pyramid-shaped) groupings of carbon atoms.

The intentional introduction of impurities into an intrinsic semiconductor for the purpose of altering its electrical, optical, and structural properties is called doping. If atoms of carbon are joined to other types of atoms to form compounds, electrical conductivity becomes altered once again. Silicon carbide, a compound of the elements silicon and carbon, exhibits nonlinear behavior: its electrical resistance decreases with increases in applied voltage! Hydrocarbon compounds (such as the molecules found in oils) tend to be very good insulators. As you can see, a simple count of valence electrons in an atom is a poor indicator of a substance’s electrical conductivity.

All metallic elements are good conductors of electricity, due to the way the atoms bond with each other. The electrons of the atoms comprising a mass of metal are so uninhibited in their allowable energy states that they float freely between the different nuclei in the substance, readily motivated by any electric field. The electrons are so mobile, in fact, that they are sometimes described by scientists as an electron gas, or even an electron sea in which the atomic nuclei rest. This electron mobility accounts for some of the other common properties of metals: good heat conductivity, malleability and ductility (easily formed into different shapes), and a lustrous finish when pure.

Thankfully, the physics behind all this is mostly irrelevant to our purposes here. Suffice it to say that some materials are good conductors, some are poor conductors, and some are in between. For now it is good enough to simply understand that these distinctions are determined by the configuration of the electrons around the constituent atoms of the material.

An important step in getting electricity to do our bidding is to be able to construct paths for current to flow with controlled amounts of resistance. It is also vitally important that we be able to prevent current from flowing where we don’t want it to, by using insulating materials. However, not all conductors are the same, and neither are all insulators. We need to understand some of the characteristics of common conductors and insulators, and be able to apply these characteristics to specific applications.

Almost all conductors possess a certain, measurable resistance (special types of materials called superconductors possess absolutely no electrical resistance, but these are not ordinary materials, and they must be held in special conditions in order to be super conductive). Typically, we assume the resistance of the conductors in a circuit to be zero, and we expect that current passes through them without producing any appreciable voltage drop. In reality, however, there will almost always be a voltage drop along the (normal) conductive pathways of an electric circuit, whether we want a voltage drop to be there or not:

In order to calculate what these voltage drops will be in any particular circuit, we must be able to ascertain the resistance of ordinary wire, knowing the wire size and diameter. Some of the following sections of this chapter will address the details of doing this.

11.2 Conductor Size

It should be common-sense knowledge that liquids flow through large-diameter pipes easier than they do through small-diameter pipes (if you would like a practical illustration, try drinking a liquid through straws of different diameters). The same general principle holds for the flow of electrons through conductors: the broader the cross-sectional area (thickness) of the conductor, the more room for electrons to flow, and consequently, the easier it is for flow to occur (less resistance).

Two Basic Varieties of Electrical Wire: Solid and Stranded

Electrical wire is usually round in cross-section (although there are some unique exceptions to this rule), and comes in two basic varieties: solid and stranded. Solid copper wire is just as it sounds: a single, solid strand of copper the whole length of the wire. Stranded wire is composed of smaller strands of solid copper wire twisted together to form a single, larger conductor. The greatest benefit of stranded wire is its mechanical flexibility, being able to withstand repeated bending and twisting much better than solid copper (which tends to fatigue and break after time).

Wire size can be measured in several ways. We could speak of a wire’s diameter, but since its really the cross-sectional area that matters most regarding the flow of electrons, we are better off designating wire size in terms of area.

These are fairly small numbers to work with, so wire sizes are often expressed in measures of thousandths-of-an-inch, or mils. For the illustrated example, we would say that the diameter of the wire was 101.9 mils (0.1019 inch times 1000). We could also, if we wanted, express the area of the wire in the unit of square mils, calculating that value with the same circle-area formula, Area = πr₂:

Calculating the Circular-mil Area of a Wire

However, electricians and others frequently concerned with wire size use another unit of area measurement tailored specifically for wire’s circular cross-section. This special unit is called the circular mil (sometimes abbreviated cmil). The sole purpose for having this special unit of measurement is to eliminate the need to invoke the factor π (3.1415927 . . .) in the formula for calculating area, plus the need to figure wire radius when you’ve been given diameter. The formula for calculating the circular-mil area of a circular wire is very simple:

Because this is a unit of area measurement, the mathematical power of 2 is still in effect (doubling the width of a circle will always quadruple its area, no matter what units are used, or if the width of that circle is expressed in terms of radius or diameter). To illustrate the difference between measurements in square mils and measurements in circular mils, I will compare a circle with a square, showing the area of each shape in both unit measures:

And for another size of wire:

Obviously, the circle of a given diameter has less cross-sectional area than a square of width and height equal to the circle’s diameter: both units of area measurement reflect that. However, it should be clear that the unit of “square mil” is really tailored for the convenient determination of a square’s area, while “circular mil” is tailored for the convenient determination of a circle’s area: the respective formula for each is simpler to work with. It must be understood that both units are valid for measuring the area of a shape, no matter what shape that may be. The conversion between circular mils and square mils is a simple ratio: there are π (3.1415927 . . .) square mils to every 4 circular mils.

Measuring Cross-Sectional Wire Area with Gauge

Another measure of cross-sectional wire area is the gauge. The gauge scale is based on whole numbers rather than fractional or decimal inches. The larger the gauge number, the skinnier the wire; the smaller the gauge number, the fatter the wire. For those acquainted with shotguns, this inversely-proportional measurement scale should sound familiar.

The table at the end of this section equates gauge with inch diameter, circular mils, and square inches for solid wire. The larger sizes of wire reach an end of the common gauge scale (which naturally tops out at a value of 1), and are represented by a series of zeros. “3/0” is another way to represent “000,” and is pronounced “triple-ought.” Again, those acquainted with shotguns should recognize the terminology, strange as it may sound. To make matters even more confusing, there is more than one gauge “standard” in use around the world. For electrical conductor sizing, the American Wire Gauge (AWG), also known as the Brown and Sharpe (B&S) gauge, is the measurement system of choice. In Canada and Great Britain, the British Standard Wire Gauge (SWG) is the legal measurement system for electrical conductors. Other wire gauge systems exist in the world for classifying wire diameter, such as the Stubs steel wire gauge and the Steel Music Wire Gauge (MWG), but these measurement systems apply to non-electrical wire use.

The American Wire Gauge (AWG) measurement system, despite its oddities, was designed with a purpose: for every three steps in the gauge scale, wire area (and weight per unit length) approximately doubles. This is a handy rule to remember when making rough wire size estimations!

For very large wire sizes (fatter than 4/0), the wire gauge system is typically abandoned for cross-sectional area measurement in thousands of circular mils (MCM), borrowing the old Roman numeral “M” to denote a multiple of “thousand” in front of “CM” for “circular mils.” The following table of wire sizes does not show any sizes bigger than 4/0 gauge, because solid copper wire becomes impractical to handle at those sizes. Stranded wire construction is favored, instead.

Wire Table For Solid, Round Copper Conductors

For some high-current applications, conductor sizes beyond the practical size limit of round wire are required. In these instances, thick bars of solid metal called busbars are used as conductors. Busbars are usually made of copper or aluminum, and are most often uninsulated. They are physically supported away from whatever framework or structure is holding them by insulator standoff mounts. Although a square or rectangular cross-section is very common for busbar shape, other shapes are used as well. Cross-sectional area for busbars is typically rated in terms of circular mils (even for square and rectangular bars!), most likely for the convenience of being able to directly equate busbar size with round wire.

11.3 Conductor Ampacity

The smaller the cross-sectional area of any given wire, the greater the resistance for any given length, all other factors being equal. A wire with greater resistance will dissipate a greater amount of heat energy for any given amount of current, the power being equal to P=I²R.

Dissipated power due to a conductor’s resistance manifests itself in the form of heat, and excessive heat can be damaging to a wire (not to mention objects near the wire), especially considering the fact that most wires are insulated with a plastic or rubber coating, which can melt and burn. Thin wires will, therefore, tolerate less current than thick wires, all other factors being equal. A conductor’s current-carrying limit is known as its ampacity.

Primarily for reasons of safety, certain standards for electrical wiring have been established within the United States, and are specified in the National Electrical Code (NEC). Typical NEC wire ampacity tables will show allowable maximum currents for different sizes and applications of wire. Though the melting point of copper theoretically imposes a limit on wire ampacity, the materials commonly employed for insulating conductors melt at temperatures far below the melting point of copper, and so practical ampacity ratings are based on the thermal limits of the insulation. Voltage dropped as a result of excessive wire resistance is also a factor in sizing conductors for their use in circuits, but this consideration is better assessed through more complex means (which we will cover in this chapter). A table derived from an NEC listing is shown for example:

Table 11.2 Copper Conductor Ampacities, in Free Air at 30 Degrees C

* = estimated values; normally, these small wire sizes are not manufactured with these insulation types

Notice the substantial ampacity differences between same-size wires with different types of insulation. This is due, again, to the thermal limits (60°, 75°, 90°) of each type of insulation material.

These ampacity ratings are given for copper conductors in “free air” (maximum typical air circulation), as opposed to wires placed in conduit or wire trays. As you will notice, the table fails to specify ampacities for small wire sizes. This is because the NEC concerns itself primarily with power wiring (large currents, big wires) rather than with wires common to low-current electronic work.

There is meaning in the letter sequences used to identify conductor types, and these letters usually refer to properties of the conductor’s insulating layer(s). Some of these letters symbolize individual properties of the wire while others are simply abbreviations. For example, the letter “T” by itself means “thermoplastic” as an insulation material, as in “TW” or “THHN.” However, the three-letter combination “MTW” is an abbreviation for Machine Tool Wire, a type of wire whose insulation is made to be flexible for use in machines experiencing significant motion or vibration.

Insulation Material

• C = Cotton
• FEP = Fluorinated Ethylene Propylene
• MI = Mineral (magnesium oxide)
• PFA = Perfluoroalkoxy
• R = Rubber (sometimes Neoprene)
• S = Silicone “rubber”
• SA = Silicone-asbestos
• T = Thermoplastic
• TA = Thermoplastic-asbestos
• TFE = Polytetrafluoroethylene (“Teflon”)
• X = Cross-linked synthetic polymer
• Z = Modified ethylene tetrafluoroethylene

Heat Rating

• H = 75 degrees Celsius
• HH = 90 degrees Celsius

Outer Covering (“Jacket”)

• N = Nylon

Special Service Conditions

• U = Underground
• W = Wet
• -2 = 90 degrees Celsius and wet

Therefore, a “THWN” conductor has Thermoplastic insulation, is Heat resistant to 75° Celsius, is rated for Wet conditions, and comes with a Nylon outer jacketing.

Letter codes like these are only used for general-purpose wires such as those used in households and businesses. For high-power applications and/or severe service conditions, the complexity of conductor technology defies classification according to a few letter codes. Overhead power line conductors are typically bare metal, suspended from towers by glass, porcelain, or ceramic mounts known as insulators. Even so, the actual construction of the wire to withstand physical forces both static (dead weight) and dynamic (wind) loading can be complex, with multiple layers and different types of metals wound together to form a single conductor. Large, underground power conductors are sometimes insulated by paper, then enclosed in a steel pipe filled with pressurized nitrogen or oil to prevent water intrusion. Such conductors require support equipment to maintain fluid pressure throughout the pipe.

Other insulating materials find use in small-scale applications. For instance, the small-diameter wire used to make electromagnets (coils producing a magnetic field from the flow of electrons) are often insulated with a thin layer of enamel. The enamel is an excellent insulating material and is very thin, allowing many “turns” of wire to be wound in a small space.

11.4 Specific Resistance

Designing Wire Resistance

Conductor ampacity rating is a crude assessment of resistance based on the potential for current to create a fire hazard. However, we may come across situations where the voltage drop created by wire resistance in a circuit poses concerns other than fire avoidance. For instance, we may be designing a circuit where voltage across a component is critical, and must not fall below a certain limit. If this is the case, the voltage drops resulting from wire resistance may cause an engineering problem while being well within safe (fire) limits of ampacity:

We know that the wire length is 2300 feet for each piece of wire, but how do we determine the amount of resistance for a specific size and length of wire? To do that, we need another formula:

This formula relates the resistance of a conductor with its specific resistance (the Greek letter “rho” (ρ), which looks similar to a lower-case letter “p”), its length (“l”), and its cross-sectional area (“A”). Notice that with the length variable on the top of the fraction, the resistance value increases as the length increases (analogy: it is more difficult to force liquid through a long pipe than a short one), and decreases as cross-sectional area increases (analogy: liquid flows easier through a fat pipe than through a skinny one). Specific resistance is a constant for the type of conductor material being calculated.

The specific resistances of several conductive materials can be found in the following table. We find copper near the bottom of the table, second only to silver in having low specific resistance (good conductivity):

Table 11.3       Specific Resistance at 20 Degrees Celsius

* = Steel alloy at 99.5 percent iron, 0.5 percent carbon

Notice that the figures for specific resistance in the above table are given in the very strange unit of “ohms-cmil/ft” (Ω-cmil/ft), This unit indicates what units we are expected to use in the resistance formula ([latex]\text{R}= \rho \ell / \text{A}[/latex]). In this case, these figures for specific resistance are intended to be used when length is measured in feet and cross-sectional area is measured in circular mils.

The metric unit for specific resistance is the ohm-meter (Ω-m), or ohm-centimeter (Ω-cm), with 1.66243 x 10_-9 Ω-meters per Ω-cmil/ft (1.66243 x 10_-7 Ω-cm per Ω-cmil/ft). In the Ω-cm column of the table, the figures are actually scaled as µΩ-cm due to their very small magnitudes. For example, iron is listed as 9.61 µΩ-cm, which could be represented as 9.61 x 10_-6 Ω-cm.

When using the unit of Ω-meter for specific resistance in the [latex]\text{R}= \rho \ell / \text{A}[/latex] formula, the length needs to be in meters and the area in square meters. When using the unit of Ω-centimeter (Ω-cm) in the same formula, the length needs to be in centimeters and the area in square centimeters.

All these units for specific resistance are valid for any material (Ω-cmil/ft, Ω-m, or Ω-cm). One might prefer to use Ω-cmil/ft, however, when dealing with round wire where the cross-sectional area is already known in circular mils. Conversely, when dealing with odd-shaped busbar or custom busbar cut out of metal stock, where only the linear dimensions of length, width, and height are known, the specific resistance units of Ω-meter or Ω-cm may be more appropriate.

11.5 Temperature Coefficient of Resistance

You might have noticed on the table for specific resistances that all figures were specified at a temperature of 20° Celsius. If you suspected that this meant specific resistance of a material may change with temperature, you were right!

Resistance values for conductors at any temperature other than the standard temperature (usually specified at 20 Celsius) on the specific resistance table must be determined through yet another formula:

The “alpha” (α) constant is known as the temperature coefficient of resistance and symbolizes the resistance change factor per degree of temperature change. Just as all materials have a certain specific resistance (at 20° C), they also change resistance according to temperature by certain amounts. For pure metals, this coefficient is a positive number, meaning that resistance increases with increasing temperature. For the elements carbon, silicon, and germanium, this coefficient is a negative number, meaning that resistance decreases with increasing temperature. For some metal alloys, the temperature coefficient of resistance is very close to zero, meaning that the resistance hardly changes at all with variations in temperature (a good property if you want to build a precision resistor out of metal wire!). The following table gives the temperature coefficients of resistance for several common metals, both pure and alloy:

Table 11.4 Temperature Coefficients of Resistance at 20 Degrees Celsius

* = Steel alloy at 99.5 percent iron, 0.5 percent carbon tys

11.6 Insulator Breakdown Voltage

The atoms in insulating materials have very tightly-bound electrons, resisting free electron flow very well. However, insulators cannot resist indefinite amounts of voltage. With enough voltage applied, any insulating material will eventually succumb to the electrical “pressure,” and then current flow will occur. However, unlike the situation with conductors where current is in linear proportion to applied voltage (given a fixed resistance), current through an insulator is quite nonlinear: for voltages below a certain threshold, virtually no current will flow, but if the applied voltage exceeds that threshold voltage (known as the breakdown voltage or dielectric strength), there will be a rush of current.

Dielectric strength is the voltage required to cause dielectric breakdown, that is, to force current through an insulating material. After dielectric breakdown, the material may or may not behave as an insulator any more, the molecular structure having been altered by the breach. There is usually a localized “puncture” of the insulating medium where the current flowed during breakdown.

The thickness of an insulating material plays a role in determining its breakdown voltage. Specific dielectric strength is sometimes listed in terms of volts per mil (1/1000 of an inch), or kilovolts per inch (the two units are equivalent), but in practice it has been found that the relationship between breakdown voltage and thickness is not exactly linear. An insulator three times as thick has a dielectric strength slightly less than 3 times as much. However, for rough estimation use, volt-per-thickness ratings are fine.

* = Materials listed are specially prepared for electrical use.